206554-22-5

Basic information

• Product Name: 1-Piperidinecarboxylic acid, 3-[(acetyloxy)methyl]-5-formyl-, phenylmethyl ester, (3S,5R)-
• CAS NO: 206554-22-5
• Molecular Formula: C17H21NO5
• Molecular Weight: 319.357
• Mol File: 206554-22-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-Piperidinecarboxylic acid, 3-[(acetyloxy)methyl]-5-formyl-, phenylmethyl ester, (3S,5R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Piperidinecarboxylic acid, 3-[(acetyloxy)methyl]-5-formyl-, phenylmethyl ester, (3S,5R)-(206554-22-5)
• EPA Substance Registry System: 1-Piperidinecarboxylic acid, 3-[(acetyloxy)methyl]-5-formyl-, phenylmethyl ester, (3S,5R)-(206554-22-5)

Safety Data

• Hazardous Substances Data: 206554-22-5(Hazardous Substances Data)

Upstream product

• 206554-33-8 (3S,5R)-3,5-Bis-hydroxymethyl-piperidine-1-carboxylic acid benzyl ester 
• 1221818-73-0 (3S,5R)-Piperidine-1,3,5-tricarboxylic acid benzyl ester dimethyl ester 
• 206761-38-8 (3S,5R)-3-acetoxymethyl-5-hydroxymethylpiperidine-1-carboxylic acid benzyl ester 

Downstream Products

• 251346-98-2 (3R,5S)-3-carboxyl-5-acetoxymethylpiperidine-1-carboxylic acid benzyl ester 
• 343565-23-1 benzyl (3R,5S)-5-acetoxymethyl-3-{[(Z)-1-trimethylsilyl-1-buten-4-yl]carbamoyl}piperidine-1-carboxylate 
• 343565-24-2 benzyl (3R,5S)-5-hydroxymethyl-3-{[(Z)-1-trimethylsilyl-1-buten-4-yl]carbamoyl}piperidine-1-carboxylate 
• 343565-26-4 benzyl (3R,5S)-5-acetoxymethyl-3-[(3-butynyl)carbamoyl]piperidine-1-carboxylate 
• 343565-19-5 (1R,4ξ,5S)-7-benzyloxycarbonyl-4-hydroxy-3-[(Z)-1-trimethylsilyl-1-buten-4-yl]-3,7-diazabicyclo[3.3.1]nonan-2-one 
• 343565-25-3 benzyl (3R,5S)-5-formyl-3-{[(Z)-1-trimethylsilyl-1-buten-4-yl]carbamoyl}piperidine-1-carboxylate 
• 343565-22-0 (1S,5R,11aS)-6,10-Dioxo-octahydro-1,5-methano-pyrido[1,2-a][1,5]diazocine-3-carboxylic acid benzyl ester 
• 343565-20-8 (1R,4ζ,5S)-7-benzyloxycarbonyl-3-(3-butyn-1-yl)-4-hydroxy-3,7-diazabicyclo[3.3.1]nonan-2-one 
• 343565-27-5 benzyl (3R,5S)-3-(3-butynylcarbamoyl)-5-(hydroxymethyl)piperidine-1-carboxylate 
• 343565-28-6 benzyl (3R,5S)-3-[(3-butynyl)carbamoyl]-5-formylpiperidine-1-carboxylate 
• 1026515-92-3 6-oxo-1,5,6,8,9,10-hexahydro-2H,4H-1,5-methano-pyrido[1,2-a][1,5]diazocine-3-carboxylic acid benzyl ester 
• 343565-21-9 6-oxo-1,5,6,8,9,11a-hexahydro-2H,4H-1,5-methano-pyrido[1,2-a][1,5]diazocine-3-carboxylic acid benzyl ester 
• 475301-86-1 (1S,5R,11aR)-3-methyldecahydro-1H-1,5-methanopyrido[1,2-a]-[1,5]diazocine 
• 475301-86-1 (+)-sparteine surrogate 

Relevant articles and documents

METHOD OF PRODUCING ALDEHYDE COMPOUND OR KETONE COMPOUND

A method of producing an aldehyde compound or a ketone compound by oxidation of a primary or secondary alcohol compound having, in the molecule, a group selected from an amino group, an azido group, a hydroxy group, and a hydroxy group protected with a protective group, the method containing the steps of: a first step including colliding and mixing the alcohol compound, a dialkyl sulfoxide having 2 to 8 carbon atoms, and an acid anhydride having 4 to 10 carbon atoms in a flow-through type reactor to cause a reaction; anda second step including colliding and mixing, in a flow-through type reactor, a trialkylamine having 3 to 10 carbon atoms and the mixture liquid obtained in the first step to cause a reaction; wherein the reactions in the first step and the second step are sequentially performed.

Synthesis of enantiopure diamine ligands related to sparteine, via scandium triflate-catalyzed imino Diels-Alder reactions

Imino Diels-Alder reactions have been investigated as a new route to sparteine analogues. The first enantioselective synthesis of two diastereoisomeric tricyclic diamines, structurally equivalent to the ABC and BCD rings of the naturally occurring alkaloid, is reported, starting from enantiopure intermediates. The effectiveness of the diamines in the lithiation of N-Boc-pyrrolidine is discussed.

Highly Enantiopure C1-Symmetric cis-Piperidine-2,5-dimethanol Monoacetates by Enzymatic Asymmetrization

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