207295-84-9

Basic information

• Product Name: VO(OC₆H₃-i-Pr₂-2,6)3
• CAS NO: 207295-84-9
• Molecular Weight: 598.74
• Mol File: 207295-84-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: VO(OC₆H₃-i-Pr₂-2,6)3(CAS DataBase Reference)
• NIST Chemistry Reference: VO(OC₆H₃-i-Pr₂-2,6)3(207295-84-9)
• EPA Substance Registry System: VO(OC₆H₃-i-Pr₂-2,6)3(207295-84-9)

Safety Data

• Hazardous Substances Data: 207295-84-9(Hazardous Substances Data)

Upstream product

• 131063-11-1 Vanadium (III) chloride-(tris-tetrahydrofuran) 
• 72727-49-2 lithium 2,6-diisopropylphenolate 
• 75-56-9 methyloxirane 
• 2078-54-8 2,6-diisopropylphenol 
• 5588-84-1 vanadium(V) oxytriisopropoxide 
• 207295-83-8 VCl(OC₆H₃-i-Pr₂-2,6)2(THF)2 
• 20156-62-1 tetrakis(trimethylsilyl)hydrazine 

Relevant articles and documents

Preparation and crystal structures of the mononuclear vanadium phenoxide complexes [VCl(OC6H3Pri2-2,6) 2(C4H8O)2] and [VO(OC6H3Pri2-2,6)3]: Procatalysts for ethylene polymerisation

The complexes [VCl(OC6H3Pri2-2,6) 2(thf)2] 1 (thf, tetrahydrofuran) and [VO(OC6H3Pri2-2,6)3] 2 have been prepared and structurally characterised. Compound 1 has a distorted trigonal bipyramidal structure with apical thf ligands [d(V-Ophenox) 1.865(2), d(V-Othf) 2.120(3) and d(V-Cl) 2.277(2) A]. It reacts with Li[SC6H2Me3-2,4,6] to give [V(SC6H2Me3-2,4,6)(OC6H 3Pri2-2,6)2(thf)2]. Compound 2, which has trigonal pyramidal geometry, is disordered about a 2-fold crystallographic axis [d(V=O) 1.564(4), d(V-Oav) 1.761(1) A]. Compounds 1 and 2 are pro-catalysts for the polymerisation of C2H4.