207409-19-6

Basic information

• Product Name: 6-[(tert-butyldimethylsilyl)oxy]-1-phenyl-2-hexyn-1-ol
• Synonyms: 6-[(tert-butyldimethylsilyl)oxy]-1-phenyl-2-hexyn-1-ol
• CAS NO: 207409-19-6
• Molecular Weight: 304.505
• Mol File: 207409-19-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 6-[(tert-butyldimethylsilyl)oxy]-1-phenyl-2-hexyn-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 6-[(tert-butyldimethylsilyl)oxy]-1-phenyl-2-hexyn-1-ol(207409-19-6)
• EPA Substance Registry System: 6-[(tert-butyldimethylsilyl)oxy]-1-phenyl-2-hexyn-1-ol(207409-19-6)

Safety Data

• Hazardous Substances Data: 207409-19-6(Hazardous Substances Data)

Upstream product

• 61362-77-4 5-[tert-butyldimethylsilyloxy]pent-1-yne 
• 100-52-7 benzaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 5390-04-5 pent-1-yn-5-ol 

Downstream Products

• 18138-77-7 (E)-2-styryltetrahydrofuran 
• 207409-37-8 Carbonic acid (Z)-6-hydroxy-1-phenyl-hex-2-enyl ester methyl ester 
• 207409-38-9 Carbonic acid (Z)-6-hydroxy-1-o-tolyl-hex-2-enyl ester methyl ester 
• 207409-31-2 Carbonic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-hex-2-enyl ester methyl ester 
• 207409-32-3 Carbonic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-1-o-tolyl-hex-2-enyl ester methyl ester 
• 1374748-11-4 C₂₂H₃₇O₅PSi 
• 1374748-29-4 tert-butyldimethyl[{6-(pentafluorophenyl)-6-phenylhexa-4,5-dien-1-yl}oxy]silane 
• 1374748-20-5 tert-butyldimethyl[{4-(pentafluorophenyl)-6-phenylhexa-4,5-dien-1-yl}oxy]silane 

Relevant articles and documents

Synthesis of Polysubstituted 2-Iodoindenes via Iodonium-Induced Cyclization of Arylallenes

A new chemoselective iodocarbocyclization of allenyl arenes was developed leading to the formation of 2-iodoindenes. In acetonitrile or nitromethane, electrophilic sources of iodine cations react selectively with the C2-C3 double bond of 1-arylallenes to give, after anti nucleophilic attack of the aromatic ring, 2-iodoindene products in high yields. Variations of the allenic skeletons revealed the high 5-endo selectivity and some competitive pathways of cyclization. Postfunctionalization reactions of the carbon-iodine bond, via Pd- and Cu-cross-couplings, gave rise to substituted indenes in good to excellent yields. (Chemical Equation Presented).

A concise access to (polyfluoroaryl)allenes by Cu-catalyzed direct coupling with propargyl phosphates

A copper-based catalyst system for the direct coupling of polyfluoroarenes with propargyl phosphates has been developed. The catalysis can provide a rapid and concise access to (polyfluoroaryl)allenes, which can be important building blocks for the synthesis of fluorinated functional materials.

Syntheses de Composes et Pyraniques par Reaction de Cyclisation Catalysee par les Complexes du Palladium(0

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