20780-35-2Relevant articles and documents
Sterols in Marine Invertebrates. 32. Isolation of 3β-(Hydroxymethyl)-A-nor-5α-cholest-15-ene, the First Naturally Occurring Sterol with a 15-16 Double Bond
Eggersdorfer, Manfred L.,Kokke, W. C. M. C.,Crandell, Christopher W.,Hochlowski, Jill E.,Djerassi, Carl
, p. 5304 - 5309 (2007/10/02)
A new A-nor sterol, 3β-(hydroxymethyl)-A-nor-5α-cholest-15-ene, with an unusual unsaturation in the Δ15 position has been found in the Pacific sponge Homaxinella trachys together with ten other A-nor sterols.The structure was elucidated by 360-MHz 1H NMR, 13C NMR, and mass spectral analysis as well as by chemical interconversion and comparision with synthetic 5α-cholest-15-en-3β-ol. 13C NMR spectra of the title compound and of various 3β-(hydroxymethyl)-A-nor-5α-cholestanes were assigned as an aid in future structure elucidation of this class of sterols.
Hydroxy-steroids. IV. The preparation and spectra of steroid olefins.
Cragg,Davey,Hall,Meakins,Richards,Whateley
, p. 1266 - 1276 (2007/10/10)
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