20805-43-0Relevant articles and documents
Synthesis of dendritic oligo(aryl sulfone)s as supports for synthesis
Taylor, Paul C.,Wall, Michael D.,Woodward, Peter R.
, p. 12314 - 12322 (2005)
A short, divergent route to G1 oligo(aryl sulfone)s and a G 2 oligo(aryl sulfone) dendrimer using nucleophilic aromatic substitution reactions is described. A range of tetrasubstituted pentasulfones are proposed for applications as homogeneous supports for synthesis. Key to achieving selectivity in the syntheses is the activation of leaving groups by sulfide to sulfone oxidation. Preparation of the G2 oligo(aryl sulfone) is low-yielding due to competition from SET processes that are interesting from a mechanistic point of view. The utility of the supports is exemplified with a four step synthesis of a dipeptide and by 'react and release' synthesis of amides.
ORGANIC SULFUR COMPOUND, PROCESS FOR PRODUCTION OF THE SAME, AND ORGANIC ELECTROLUMINESCENCE ELEMENT UTILIZING THE SAME
-
Page/Page column 22, (2011/06/26)
Disclosed is an organic sulfur compound represented by general formula (a1) [wherein, A represents -S-, -S(O)- or -S(O)2-; Z1 and Z4 independently represent a trivalent aromatic hydrocarbon group, or the like; Z2 and Z3 independently represent a bivalent aromatic hydrocarbon group, or the like; Ar1, Ar2, Ar3 and Ar4 independently represent an aromatic hydrocarbon group, or the like; and n represents a number of 0 or 1] or general formula (b1) [wherein A is as defined above; Z5 represents a trivalent aromatic hydrocarbon group, or the like; Ar represents an aromatic hydrocarbon group having a valency of m, or the like, Ar1 and Ar2 are as defined above; and m represents a number of 2 of 3]. The compound is useful as an electron transport material, a hole blocking material or a host material for an organic electroluminescence element.