20915-78-0Relevant articles and documents
Oxone-acetone mediated Wacker-type oxidation of benzo-fused olefins
Phatake, Ravindra S.,Ramana, Chepuri V.
, p. 3868 - 3871 (2015)
Herein we disclose a novel application of the oxone-acetone combination for the Wacker-type oxidation of indenes and dihydronaphthalenes leading, respectively, to indan-2-ones and 2-tetralones. The amount of the base employed in the reaction seems to switch the reaction path from dioxygenation to Wacker-type oxidation. Control experiments suggest that the reaction is not proceeding via the epoxide route and also that there is no role of trace amounts of metals present in the reagents on the current oxidation.
Hydroborations: A new route for the preparation of 1-alkyl- (or aryl) 2-tetralones
Kirkiacharian,Koutsourakis
, p. 737 - 742 (2007/10/02)
The hydroboration followed by chromic acid oxidation of 1-alkyl- and 1-aryl-3,4-dihydronaphthalenes leads to the corresponding 1-alkyl- (or aryl)2-tetralones (1-substituted 3,4-dihydronaphthalen-2(1H)-ones.