209391-60-6

Basic information

• Product Name: Benzene, 1-[(1-chloro-2,2-diphenylethenyl)sulfinyl]-4-methyl-
• CAS NO: 209391-60-6
• Molecular Formula: C21H17ClOS
• Molecular Weight: 352.884
• Mol File: 209391-60-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(1-chloro-2,2-diphenylethenyl)sulfinyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(1-chloro-2,2-diphenylethenyl)sulfinyl]-4-methyl-(209391-60-6)
• EPA Substance Registry System: Benzene, 1-[(1-chloro-2,2-diphenylethenyl)sulfinyl]-4-methyl-(209391-60-6)

Safety Data

• Hazardous Substances Data: 209391-60-6(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 24824-93-9 chloromethyl p-tolyl sulfoxide 
• 209391-91-3 2-Chloro-1,1-diphenyl-2-(toluene-4-sulfinyl)-ethanol 
• 209391-96-8 Acetic acid 2-chloro-1,1-diphenyl-2-(toluene-4-sulfinyl)-ethyl ester 

Downstream Products

• 501-65-5 diphenyl acetylene 
• 4541-89-3 2-chloro-1,1-diphenylethene 
• 1726-14-3 1,1-diphenyl-1-butene 
• 625844-85-1 2-amino-3-(4-methoxyphenyl)-5,5-diphenylcyclopenta-1,3-diene-1-carbonitrile 
• 625844-84-0 2-amino-3-ethyl-5,5-diphenylcyclopenta-1,3-diene-1-carbonitrile 
• 625844-83-9 2-amino-3-methyl-5,5-diphenylcyclopenta-1,3-diene-1-carbonitrile 
• 289680-78-0 4-chloro-3,3-diphenyl-4-(p-tolylsulfinyl)butyronitrile 
• 18523-73-4 2,2-diphenylethenyl p-tolyl sulfide 
• 224319-39-5 2-amino-1-cyano-5,5-diphenyl-1,3-cyclopentadiene 

Relevant articles and documents

Fritsch-Buttenberg-Wiechell rearrangement of magnesium alkylidene carbenoids leading to the formation of alkynes

A series of 1-heteroatom-substituted vinyl p-tolyl sulfoxides were prepared and treated with organometallic reagents to evaluate which combination of sulfoxides and organometallic reagents yielded alkynes the most efficiently. The use of 1-chlorovinyl p-tolyl sulfoxide and isopropylmagnesium chloride was optimal for this purpose. A variety of 1-chlorovinyl p-tolyl sulfoxides were prepared from carbonyl compounds and chloromethyl p-tolyl sulfoxide and were converted into alkynes via the sulfoxide/magnesium exchange reaction and subsequent Fritsch-Buttenberg-Wiechell (FBW) rearrangement of the resulting magnesium alkylidene carbenoids. The mechanism of the FBW rearrangement of magnesium alkylidene carbenoids was studied by using13C-labeled sulfoxides and by using DFT calculations.