20951-13-7

Basic information

• Product Name: 4-chloro-1-methoxy-2-(methylsulfonyl)benzene
• Synonyms: 4-chloro-1-methoxy-2-(methylsulfonyl)benzene
• CAS NO: 20951-13-7
• Molecular Weight: 220.677
• Mol File: 20951-13-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-chloro-1-methoxy-2-(methylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-chloro-1-methoxy-2-(methylsulfonyl)benzene(20951-13-7)
• EPA Substance Registry System: 4-chloro-1-methoxy-2-(methylsulfonyl)benzene(20951-13-7)

Safety Data

• Hazardous Substances Data: 20951-13-7(Hazardous Substances Data)

Upstream product

• 744154-58-3 5-chloro-2-methoxy-benzenesulfinic acid 
• 77-78-1 dimethyl sulfate 
• 23385-57-1 4-Chlor-2-methylmercapto-1-methoxy-benzol 
• 67-56-1 methanol 
• 66640-63-9 2,5-dichlorophenyl methyl sulfone 
• 124-41-4 sodium methylate 
• 22952-33-6 5-chloro-2-methoxybenzenesulfonohydrazide 
• 868-85-9 Dimethyl phosphite 

Downstream Products

• 20951-37-5 4-chloro-2-methanesulfonyl-phenol 
• 20951-16-0 (4-Chloro-2-methanesulfonyl-phenoxy)-acetic acid ethyl ester 

Relevant articles and documents

High Chemoselectivity in the Construction of Aryl Methyl Sulfones via an Unexpected C-S Bond Formation between Sulfonylhydrazides and Dimethyl Phosphite

A highly chemoselective route to aryl methyl sulfones via an unexpected C S bond formation between sulfonylhydrazides and dimethyl phosphite catalyzed by NaI under mild conditions has been established. This transformation provides an alternative and metal-free pathway to acquire various aryl methyl sulfones in good to excellent yields. Notably, dimethyl phosphite was employed as a stable and readily available alkyl source.