20993-78-6

Basic information

• Product Name: (1R,2S)-2-methylcyclohexanol acetate
• Synonyms: (1R,2S)-2-methylcyclohexanol acetate
• CAS NO: 20993-78-6
• Molecular Weight: 156.225
• Mol File: 20993-78-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1R,2S)-2-methylcyclohexanol acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-2-methylcyclohexanol acetate(20993-78-6)
• EPA Substance Registry System: (1R,2S)-2-methylcyclohexanol acetate(20993-78-6)

Safety Data

• Hazardous Substances Data: 20993-78-6(Hazardous Substances Data)

Upstream product

• 108-22-5 Isopropenyl acetate 
• 7443-70-1 cis-2-methylcyclohexanol 
• 286-08-8 2,7,7-trimethyltricyclo[4.1.1.0^2,4]octane 
• 64-19-7 acetic acid 
• 591-49-1 1-methylcyclohex-1-ene 
• 7443-52-9 (+/-)-trans-2-methylcyclohexanol 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 50539-18-9 (+/-)-cis-2-methylcyclohexanol acetate 

Downstream Products

• 15288-15-0 (1R,2R)-2-methylcyclohexanol acetate 
• 152140-96-0 (1S,2S)-(+)-trans-2-methylcyclohexanyl acetate 
• 19043-03-9 (1R,2R)-(-)-trans-2-methylcyclohexanol 
• 15963-37-8 trans-2-methylcyclohexanol 
• 591-49-1 1-methylcyclohex-1-ene 
• 591-48-0 3-methyl-1-cyclohexene 

Relevant articles and documents

Enantioselective hydrolyses with Yarrowia lipolytica: A versatile strain for esters, enol esters, epoxides, and lactones

Racemic secondary esters 1-3, γ-lactones 8-9, and styrene oxide 7 are kinetically resolved via hydrolysis with Yarrowia lipolytica YL2 strain. The enantioselective hydrolysis of prochiral enol esters 4-6 to the corresponding homochiral carbonyl compounds 13-15 is also described. Subsequent reduction of the ketone 13 and of the aldehyde 15 can be avoided using lyophilised cells.

Anti-Markovnikov Addition of Nucleophiles to a Non-conjugated Olefin via Single Electron Transfer Photochemistry

Nucleophilic solvent has been added regiospecifically in an anti-Markovnikov manner to a simple non-conjugated olefin, 1-methylcyclohexene, through single electron transfer induced photochemistry using the 1-cyanonaphthalene - biphenyl pair for achieving photooxidation.