2100-38-1Relevant articles and documents
Oxidative C-H Acyloxylation of Acetone with Carboxylic Acids under Iodine Catalysis
Zhou, Xiao-Yu,Chen, Xia
supporting information, p. 1654 - 1662 (2021/01/21)
Iodine-catalyzed oxidative C(sp 3)-H acyloxylation of acetone with carboxylic acids has been developed. The method employs iodide as catalyst and sodium chlorite as oxidant. Substituted benzoic acids, naphthoic acids and heteroaromatic carboxyl
1,2-Dibromoethane and KI mediated α-acyloxylation of ketones with carboxylic acids
Wang, Xujie,Li, Gangsheng,Yang, Yanan,Jiang, Jianshuang,Feng, Ziming,Zhang, Peicheng
supporting information, p. 711 - 714 (2019/09/30)
The 1,2-dibromoethane- and KI-mediated α-acyloxylation of ketones is reported in moderate to good yield without the use of transition metals and strong oxidants. Various acids are well tolerated with wide functional group compatibility. An 1,2-dibromoethane- and KI-catalysed reaction mechanism is proposed based on the results of control experiments.
Synthesis and hydrolysis of acyloxy-2-oxopropanes
Schwenker,Stiefvater
, p. 547 - 550 (2007/10/02)
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