210106-84-6Relevant articles and documents
The mechanism of cleavage under basic conditions of succinyl-anchored oligonucleotides
Palom, Yolanda,Grandas, Anna,Pedroso, Enrique
, p. 1177 - 1182 (1998)
Studies with a model compound provide direct evidence that cleavage of succinyl-anchored oligonucleotides takes place by intramolecular nucleophilic attack of the conjugate base of the succinamide at the ester carbonyl group. An N-substituted succinamide is exclusively formed with piperidine, DBU and TBAF, but when ammonia is used this general mechanism seems to coexist with ammonolysis of the succinate ester. Cleavage with TBAF is extremely fast.
Novel α-amino acid-based hydroxamic acid ligands for vanadium-catalyzed asymmetric epoxidation of allylic alcohols [2]
Hoshino,Yamamoto
, p. 10452 - 10453 (2007/10/03)
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