210306-18-6Relevant articles and documents
Use of molecular recognition to drive chemical evolution: Mechanisms of an automated genetic algorithm implementation
Eliseev, Alexey V.,Nelen, Marina I.
, p. 825 - 834 (1998)
A detailed description is provided for a new general approach that allows production of amplified amounts of effective noncovalent binders from pools of compounds that can exist in a dynamic equilibrium. This approach involves a) selective binding of the
New solid-state Eu(III)-containing metallo-supramolecular polymers: Morphology control and optical wave-guiding properties
Duerrbeck, Andre,Gorelik, Sergey,Hobley, Jonathan,Yong, Anna Marie,Subramanian, Gomathy Sandhya,Hor, Andy,Long, Nicholas
, p. 8992 - 9002 (2015/09/01)
Herein, we report the solution phase self-assembly between Eu(iii) and a rigid ditopic tridentate terpyridine ligand which results in the formation of supramolecular metallo-networks in the solid state. Depending on the ligand to metal ratio used for the initial self-assembly process, the morphology of these materials can be altered from one-dimensional micron-sized fibres to a three-dimensional coordination network. The terpyridine-based ditopic ligand can act as an efficient sensitizer for Eu(iii) emission whereby the emission lifetimes and ligand triplet state energies of the metallo-polymers strongly depend on the ligand to metal ratio. The obtained micron-sized fibres can act as an efficient optical wave-guide for Eu(iii) emission.
Convenient synthesis of bis-bipyridines and bis-terpyridines bridged by phenyl and biphenyl tethers
Baba,Wang,Won Yong Kim,Strong,Schmehl
, p. 1029 - 1036 (2007/10/02)
A simple three step preparation of phenyl bridged bis-2,2'-bipyridine and bis-2,2':6',2''-terpyridine from readily available reagents is described. The compounds have the potential to serve as rigid bridging ligands for the preparation of redox and photoactive supramolecular complexes of transition metals.