210978-95-3

Basic information

• Product Name: 2-Benzenesulfinylmethyl-furan-3-carboxylic acid methyl ester
• Synonyms: 2-Benzenesulfinylmethyl-furan-3-carboxylic acid methyl ester
• CAS NO: 210978-95-3
• Molecular Weight: 264.302
• Mol File: 210978-95-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Benzenesulfinylmethyl-furan-3-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Benzenesulfinylmethyl-furan-3-carboxylic acid methyl ester(210978-95-3)
• EPA Substance Registry System: 2-Benzenesulfinylmethyl-furan-3-carboxylic acid methyl ester(210978-95-3)

Safety Data

• Hazardous Substances Data: 210978-95-3(Hazardous Substances Data)

Upstream product

• 139308-33-1 2-Phenylsulfanylmethyl-furan-3-carboxylic acid methyl ester 
• 6141-58-8 methyl 2-methyl-3-furancarboxylate 
• 53020-08-9 2-bromomethylfuran-3-carboxylic acid methyl ester 

Relevant articles and documents

Anionic [4+2] cycloaddition strategy to linear furocoumarins: Synthesis of 8 methoxypsoralen and its isoster

The surfoxide esters 14 and 20d are successfully annulated with bicyclic enone 8 in the presence of (t)BuOLi to provide the pentacyclic ketones 9a and 21a respectively in good yields (≤70%). Flash vacuum pyrolysis of O-methyl derivatives 9b and 21b at - 5000 C/. 1 mm provide furoindacenones 16b and 22b respectively, which in turn are convertible to furocoumarins 1 and 3.