21139-18-4

Basic information

• Product Name: 2(1H)-Pyrimidinone, 4,6-dimethyl-1-phenyl-
• CAS NO: 21139-18-4
• Molecular Formula: C12H12N2O
• Molecular Weight: 200.24
• Mol File: 21139-18-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2(1H)-Pyrimidinone, 4,6-dimethyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(1H)-Pyrimidinone, 4,6-dimethyl-1-phenyl-(21139-18-4)
• EPA Substance Registry System: 2(1H)-Pyrimidinone, 4,6-dimethyl-1-phenyl-(21139-18-4)

Safety Data

• Hazardous Substances Data: 21139-18-4(Hazardous Substances Data)

Upstream product

• 74152-15-1 2-oxo-1-phenyl-4,6-dimethyl-1,2,3,4-tetrahydropyrimidine 
• 83786-49-6 4-(3-ethoxypropyl)-6-methyl-1-phenylpyrimidin-2(1H)-one 
• 90128-43-1 2-phenylimino-4-(N'-propylureido)pent-3-ene 
• 64-10-8 phenyl carbamate 
• 123-54-6 acetylacetone 
• 1118-66-7 4-Aminopent-3-en-2-one 
• 103-72-0 phenyl isothiocyanate 
• 74359-94-7 1-oxo-1-phenyl-4,6-dimethyl-1,2,3,6-tetrahydropyrimidine 
• 61404-64-6 6-methyl-1-phenyl-4-propylpyrimidin-2(1H)-one 

Downstream Products

• 83786-46-3 4,6-Dimethyl-3-phenyl-4-(tetrahydro-furan-2-yl)-3,4-dihydro-1H-pyrimidin-2-one 
• 68230-25-1 4,6-dimethyl-3-phenyl-1,3-diaza-bicyclo[2.2.0]hex-5-en-2-one 
• 93238-50-7 4-methyl-6-phenylethyl-1-phenyl-2(1H)-pyrimidinone 
• 93238-53-0 4-methyl-6-<2-(1,3-diphenyl)propyl>-1-phenyl-2(1H)-pyrimidinone 
• 78072-13-6 4,6-dimethyl-3-phenyl-5-phenylthio-1,3-diazabicyclo<2.2.0>hexan-2-one 
• 68230-26-2 3-phenyl-4,6-dimethyl-2-oxo-1,3-diazabicyclo<2.2.0>hexane 
• 2603-10-3 N-phenyl methyl carbamate 
• 10199-63-0 1-(3,5-dimethyl-1H-pyrazol-1-yl)ethanone 
• 300-87-8 3,5-dimethyl-1,2-oxazole 
• 26567-78-2 (Z)-4-(phenylamino)-3-penten-2-one 
• 74152-15-1 2-oxo-1-phenyl-4,6-dimethyl-1,2,3,4-tetrahydropyrimidine 
• 74359-94-7 1-oxo-1-phenyl-4,6-dimethyl-1,2,3,6-tetrahydropyrimidine 
• 74152-06-0 3,4,5,6-tetrahydro-4,6-dimethyl-1-phenyl-2-(1H)pyrimidinone 
• 74360-10-4 4,6-dimethyl-1-phenylpyrimidine-2(1H)-thione 

Relevant articles and documents

Crystal engineering of neutral N-arylpyrimidinones and their HCI and HNO3 adducts with a C-H···O supramolecular synthon. Implications for non-linear optics

In a previous crystallographic study of some N-arylpyrimidinones 1, we noted that: (1) C-H···O hydrogen bonds connect molecules in a linear array; (2) the charge transfer axis of the chromophore is aligned with the main symmetry operator of point groups 2

Photochemical Ring Opening of Pyrimidin-2(1H)-ones. Part 2.

The photochemical reactions of 1-aryl-4,6-disubstituted pyrimidin-2(1H)-ones have been examined.Irradiation of 1-aryl-4,6-disubstituted pyrimidin-2(1H)-ones (1)-(6) in benzene in the presence of primary or secondary amines gave arylimine products(10)-(15)

PHOTOCHEMICAL REACTION OF PYRIMIDIN-2(1H)-ONES: INTER- AND INTRAMOLECULAR HYDROGEN ABSTRACTION BY THE NITROGEN OF IMINO GROUP

Irradiation of 1-methyl-4,6-diphenylpyrimidin-2(1H)-one (1a) in acyclic or cyclic ethers afforded the C-C bonded 1:1-adducts (2a-c) of 1a and ether via intermolecular hyrogen abstraction of the excited imino nitrogen of 1a, while irradiation of 1-phenyl-4-(3-ethoxypropyl)-6-methylpyrimidin-2(1H)-one (1g) gave 1-phenyl-4,6-dimethylpyrimidin-2(1H)-one (1d) via intramolecular hydrogen abstraction of the excited imino nitrogen of 1g, in addition to 2-oxo-1,3-diazabicyclohex-5-ene derivative (3g).