21192-57-4Relevant articles and documents
Synthesis of 1-Tri(di)fluoromethyl 1,4-Diketones Enabled by Radical Brook Rearrangement
Chen, Xiang,Liu, Shanshan,Shen, Xiao,Zhang, Jianjun,Zhu, Zhihong
supporting information, p. 4927 - 4931 (2021/09/30)
Herein, we disclose the first and simple one-pot-two-step process to the synthesis of 1-difluoromethyl 1,4-diketones, through Mn-catalyzed radical Brook rearrangement. The methodology is also amenable to the synthesis of 1-trifluoromethyl 1,4-diketones. T