21213-18-3Relevant articles and documents
Aryne triggered [2,3]-sigmatropic rearrangement of allyl and propargyl thioethers
Tan, Jiajing,Zheng, Tianyu,Xu, Kun,Liu, Changyao
supporting information, p. 4946 - 4950 (2017/07/10)
An efficient protocol for [2,3]-sigmatropic rearrangement of allyl and propargyl thioethers is reported. The key sulfonium ylide intermediate is in situ formed via S-arylation of arynes. This transition metal-free method allows for ready access to a wide