212475-58-6

Basic information

• Product Name: (2-Allylsulfanyl-phenyl)-carbamic acid tert-butyl ester
• CAS NO: 212475-58-6
• Molecular Weight: 265.376
• Mol File: 212475-58-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-Allylsulfanyl-phenyl)-carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Allylsulfanyl-phenyl)-carbamic acid tert-butyl ester(212475-58-6)
• EPA Substance Registry System: (2-Allylsulfanyl-phenyl)-carbamic acid tert-butyl ester(212475-58-6)

Safety Data

• Hazardous Substances Data: 212475-58-6(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 77053-20-4 2-(2-propen-1-ylsulfanyl)aniline 

Downstream Products

• 212475-70-2 N-(2-Allylsulfanyl-phenyl)-N-benzyl-2-diazo-malonamic acid ethyl ester 
• 212475-78-0 7-Allylsulfanyl-1-benzyl-2-oxo-2,3-dihydro-1H-indole-3-carboxylic acid ethyl ester 
• 212475-66-6 2-allylthio-N-benzylaniline 
• 212475-62-2 (2-Allylsulfanyl-phenyl)-benzyl-carbamic acid tert-butyl ester 

Relevant articles and documents

Ligand effects in the metal catalysed reactions of N-aryldiazoamides: Ylide formation vs. insertion reactions

Diazoamides 1a and 1b were prepared from 2-(O-allyl)- and 2-(S-allyl) anilines 2 respectively. Copper(II) catalysed decomposition of 1 resulted in formation of benzofused heterocycles 7 by [2,3]-rearrangement of the intermediate ylide. Rhodium(II) perfluorbutyramide catalysed reaction, however, gave mainly the indoles 8, 9 whereas rhodium(II) acetate catalysed reaction resulted in a mixture of products, with β-lactams formed by intramolecular C-H insertion predominating. Catalysed decomposition of N- pyridyl diazoamide 13 gave the stable pyridinium ylide 14.