21254-74-0

Basic information

• Product Name: 2,4,6-tris(piperidin-1-yl)-1,3,5-triazine
• Synonyms: 2,4,6-tris(piperidin-1-yl)-1,3,5-triazine
• CAS NO: 21254-74-0
• Molecular Weight: 330.476
• EINECS: -0
• Mol File: 21254-74-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2,4,6-tris(piperidin-1-yl)-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-tris(piperidin-1-yl)-1,3,5-triazine(21254-74-0)
• EPA Substance Registry System: 2,4,6-tris(piperidin-1-yl)-1,3,5-triazine(21254-74-0)

Safety Data

• Hazardous Substances Data: 21254-74-0(Hazardous Substances Data)

Usage

General Description

2,4,6-tris(piperidin-1-yl)-1,3,5-triazine is a chemical compound with the molecular formula C21H39N7. It is a nitrogen-containing heterocyclic compound and is commonly used as a crosslinking agent in the synthesis of polymers and resins. The presence of the piperidine groups on the triazine ring makes it an effective molecule for promoting adhesion and cohesion in various materials. It is also used in the manufacturing of adhesives, coatings, and plastics, and has been studied for its potential use in drug delivery systems and as a catalyst in organic synthesis. However, it is important to handle this compound with caution as it may pose health and environmental hazards if not used properly.

Upstream product

• 626-67-5 N-methylcyclohexylamine 
• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 1530-87-6 1-piperidinylcarbonnitrile 
• 103-70-8 Formanilid 
• 110-89-4 piperidine 
• 5759-58-0 2,4,6-tris(methylthio)-1,3,5-triazine 

Downstream Products

• 110-89-4 piperidine 
• 108-80-5 isocyanuric acid 

Relevant articles and documents

Reactions of bis(silyl-substituted) methyllithium with α-hydrogen- free nitriles into 1,3,5-triazines

Bis(silyl-substituted) methyllithium has been found to catalyze a conversion of α-hydrogen-free nitriles directly to yield 2,4,6-trisubsituted s-triazines. The generally high yields and relatively mild reaction conditions of this procedure suggest an alternative to other aromatic nitrile cyclotrimerization reactions. Silicotropic rearrangements from C to N or N to N and an unusual elimination of LiCR2R (R=SiMe3, R=SiMe2NMe2) were observed.

Synthesis, Spectra, and Theoretical Investigations of 1,3,5-Triazines Compounds as Ultraviolet Rays Absorber Based on Time-Dependent Density Functional Calculations and three-Dimensional Quantitative Structure-Property Relationship

A series of 1,3,5-triazines were synthesized and their UV absorption properties were tested. The computational chemistry methods were used to construct quantitative structure-property relationship (QSPR), which was used to computer aided design of new 1,3,5-triazines ultraviolet rays absorber compounds. The experimental UV absorption data are in good agreement with those predicted data using the Time-dependent density functional theory (TD-DFT) [B3LYP/6–311 + G(d,p)]. A suitable forecasting model (R > 0.8, P 0.0001) was revealed. Predictive three-dimensional quantitative structure-property relationship (3D-QSPR) model was established using multifit molecular alignment rule of Sybyl program, which conclusion is consistent with the TD-DFT calculation. The exceptional photostability mechanism of such ultraviolet rays absorber compounds was studied and confirmed as principally banked upon their ability to undergo excited-state deactivation via an ultrafast excited-state proton transfer (ESIPT). The intramolecular hydrogen bond (IMHB) of 1,3,5-triazines compounds is the basis for the excited state proton transfer, which was explored by IR spectroscopy, UV spectra, structural and energetic aspects of different conformers and frontier molecular orbitals analysis.

A convenient method for the preparation of some new derivatives of 1,3,5-s-triazine under solvent free condition

Nucleophilic reactions on cyanuric chloride were carried out under solvent free conditions to give 1,3,5-s-triazine derivatives with excellent yields.