21310-05-4Relevant articles and documents
A novel copper-catalyzed reductive coupling of N-tosylhydrazones with H-phosphorus oxides
Wu, Lei,Zhang, Xiao,Chen, Qing-Qing,Zhou, An-Kun
supporting information, p. 7859 - 7862 (2013/06/27)
We report here a novel C(sp3)-P bonds formation via copper-catalyzed reductive coupling of N-tosylhydrazones with H-phosphorus oxides. A variety of aliphatic and aromatic substrates bearing electron-rich and electron-deficient substituents affords phosphine oxide derivatives with moderate to good yields. This work suggests a new transformation of aldehydes/ketones via N-tosylhydrazones to organophosphorus compounds.
