213127-92-5

Basic information

• Product Name: (2S)-2-{[(benzyloxy)carbonyl]amino}-3-{4-[(diethoxyphosphoryl)methyl]phenyl}propyl acetate
• Synonyms: (2S)-2-{[(benzyloxy)carbonyl]amino}-3-{4-[(diethoxyphosphoryl)methyl]phenyl}propyl acetate
• CAS NO: 213127-92-5
• Molecular Weight: 477.494
• Mol File: 213127-92-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S)-2-{[(benzyloxy)carbonyl]amino}-3-{4-[(diethoxyphosphoryl)methyl]phenyl}propyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2-{[(benzyloxy)carbonyl]amino}-3-{4-[(diethoxyphosphoryl)methyl]phenyl}propyl acetate(213127-92-5)
• EPA Substance Registry System: (2S)-2-{[(benzyloxy)carbonyl]amino}-3-{4-[(diethoxyphosphoryl)methyl]phenyl}propyl acetate(213127-92-5)

Safety Data

• Hazardous Substances Data: 213127-92-5(Hazardous Substances Data)

Upstream product

• 213127-76-5 3-acetoxy-2-{4-[(diethoxyphosphoryl)methyl]benzyl}propyl acetate 
• 213127-80-1 (2R)-2-[4-(diethoxyphosphorylmethyl)benzyl]-3-hydroxypropyl acetate 
• 213127-66-3 dimethyl 2-[(4-diethoxyphosphorylmethyl)benzyl]malonate 
• 213127-70-9 diethyl {4-[3-hydroxy-2-(hydroxymethyl)propyl]phenyl}methylphosphonate 
• 108228-81-5 4-(diethoxyphosphorylmethyl)-1-bromomethyl-phenyl 
• 3762-25-2 diethyl 4-methylbenzylphosphonate 
• 213127-90-3 (2S)-3-acetoxy-2-{4-[(diethoxyphosphoryl)methyl]benzyl}propanoic acid 
• 100-51-6 benzyl alcohol 

Downstream Products

• 213127-94-7 (2S)-2-[(tert-butoxycarbonyl)amino]-3-{4-[(diethoxyphosphoryl)methyl]phenyl}propyl acetate 
• 142348-55-8 (2S)-2-[(tert-butoxycarbonyl)amino]-3-{4-[(diethoxyphosphoryl)methyl]phenyl}propanoic acid 
• 213127-96-9 diethyl [(4-{(2S)-2-[(tert-butoxycarbonyl)amino]-3-hydroxypropyl}phenyl)methyl]phosphonate 

Relevant articles and documents

Enzymatic desymmetrization of prochiral 2-benzyl-1,3-propanediol derivatives: A practical chemoenzymatic synthesis of novel phosphorylated tyrosine analogues

(Phosphonomethyl)phenylalanine (Pmp) and (phosphonodifluoromethyl)phenylalanine (F2Pmp) as well as their β-amino acid congeners were prepared as a protecting variant amenable to the peptide synthesis from readily available 2-benzyl-1,3-propandiols possessing either a diethylphosphonomethyl- or diethylphosphonodifluoromethyl functionality at the para-position via the lipase-catalyzed desymmetrization.