213776-53-5

Basic information

• Product Name: N-{2-[Bis-(1H-pyrrol-2-yl)-methyl]-3-methoxy-phenyl}-2,2-dimethyl-propionamide
• CAS NO: 213776-53-5
• Molecular Weight: 351.448
• Mol File: 213776-53-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-{2-[Bis-(1H-pyrrol-2-yl)-methyl]-3-methoxy-phenyl}-2,2-dimethyl-propionamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-{2-[Bis-(1H-pyrrol-2-yl)-methyl]-3-methoxy-phenyl}-2,2-dimethyl-propionamide(213776-53-5)
• EPA Substance Registry System: N-{2-[Bis-(1H-pyrrol-2-yl)-methyl]-3-methoxy-phenyl}-2,2-dimethyl-propionamide(213776-53-5)

Safety Data

• Hazardous Substances Data: 213776-53-5(Hazardous Substances Data)

Upstream product

• 109-97-7 pyrrole 
• 82673-65-2 N-(2-formyl-3-methoxyphenyl)pivalamide 

Relevant articles and documents

New Enzyme Models of Chloroperoxidase: Improved Stability and Catalytic Efficiency of Iron Porphyrinates Containing a Thiolato Ligand

The heme-thiolate protein chloroperoxidase (CPO) catalyzes the chlorination of activated C-H bonds. A reaction mechanism is proposed for this enzymatic transformation (Scheme 1), and a new iron(III) porphyrinate complex 13 is synthesized containing pentafluorophenyl groups at two meso-positions and a thiophenolato ligand coordinating to the Fe-atom (Schemes 2 and 3). Due to the presence of the electron-withdrawing substituents, the catalyst 13 is appreciably resistant to oxidants (HOCl) and chlorinates, e.g., monochlorodimedone (5), with turnover numbers up to 1530. The redox potential of 13, E0 = - 134 mV, and the Soret band (λmax 448 nm) of the CO adduct of the reduced state of 13 are close to the corresponding values of the enzyme CPO.