213978-60-0Relevant articles and documents
Synthetic studies towards phorboxazole A. A convergent synthesis of the C31-C46 polyene oxane-hemiacetal side chain
Pattenden, Gerald,Plowright, Alleyn T.,Tornos, James A.,Ye, Tao
, p. 6099 - 6102 (1998)
A convergent and stereoselective synthesis of the C31-C46 side chain unit in the marine natural product phorboxazole A, which accommodates five asymmetric centres, three carbon-to-carbon double bonds and an oxane- hemiacetal unit, is described.
Fluorous mixture synthesis of four stereoisomers of the C21-C40 fragment of tetrafibricin
Zhang, Kai,Curran, Dennis P.
supporting information; experimental part, p. 667 - 671 (2010/12/18)
Four stereoisomers of the C21-C40 fragment are synthesized in a single exercise with the aid of fluorous tagging to encode configurations at C37 and C33. After demixing and detagging, the isomers were found to have substantially identical 1H NM