214214-66-1

Basic information

• Product Name: diethyl 2-bromomethyl-2-phenylmalonate
• Synonyms: diethyl 2-bromomethyl-2-phenylmalonate
• CAS NO: 214214-66-1
• Molecular Weight: 329.191
• Mol File: 214214-66-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diethyl 2-bromomethyl-2-phenylmalonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2-bromomethyl-2-phenylmalonate(214214-66-1)
• EPA Substance Registry System: diethyl 2-bromomethyl-2-phenylmalonate(214214-66-1)

Safety Data

• Hazardous Substances Data: 214214-66-1(Hazardous Substances Data)

Upstream product

• 83-13-6 diethyl 2-phenylmalonate 
• 74-95-3 1,1-dibromomethane 

Downstream Products

• 1197214-58-6 C₁₄H₁₇⁽²⁾HO₄ 
• 607-81-8 diethyl 2-benzylmalonate 
• 34009-61-5 diethyl 2-methyl-2-phenylmalonate 
• 34861-81-9 diethyl phenylsuccinate 

Relevant articles and documents

Electrochemical catalytic carbon-skeleton rearrangement mediated by imine/oxime-type B12 model complex

An electrochemical carbon-skeleton rearrangement of methylmalonate skeleton to succinate was successfully mediated by an imine/oxime-type cobalt complex using diethyl 2-bromomethyl-2- phenylmalonate as a model substrate of a coenzyme B12-dependent enzymatic reaction. Cyclic voltammetric and mass spectrometric studies revealed that this electrocatalysis of the alkyl bromide with 1,2-migration of a carboxylic ester group was achieved by the duet redox process between the reduction of the monoalkylated complex and the oxidation of the dialkylated complex.