214219-43-9

Basic information

• Product Name: Trimethyl(3-(phenylthio)prop-1-ynyl)germane
• Synonyms: Trimethyl(3-(phenylthio)prop-1-ynyl)germane
• CAS NO: 214219-43-9
• Molecular Weight: 264.915
• Mol File: 214219-43-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trimethyl(3-(phenylthio)prop-1-ynyl)germane(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethyl(3-(phenylthio)prop-1-ynyl)germane(214219-43-9)
• EPA Substance Registry System: Trimethyl(3-(phenylthio)prop-1-ynyl)germane(214219-43-9)

Safety Data

• Hazardous Substances Data: 214219-43-9(Hazardous Substances Data)

Upstream product

• 5651-88-7 phenyl propargyl sulfide 
• 1066-38-2 iodotrimethylgermane 

Relevant articles and documents

Iridium complex catalyzed germylative coupling reaction between alkynes and iodogermanes-a new route to alkynylgermanium and alkynylgermasilicon compounds

The new reaction of terminal alkynes with iodogermanes proceeding in the presence of an IrI-complex [{Ir(μ-Cl)(CO)2}2] (I) and NEt(iPr)2, as a hydrogen iodide acceptor, leads to the formation of functionalized alkynylgermanes. This reaction occurs via direct activation of the Csp-H bond in the starting alkyne. Detailed stoichiometric experiments using [Ir(cod)(CCPh)(PCy3)] (IVa) and iodogermane were performed and resulted in a proposal of a reasonable mechanism for the germylative coupling reaction between alkynes and iodogermanes.