2143-67-1Relevant articles and documents
Multifunctional Antioxidants with High Activity at Elevated Temperatures Based on Intramolecular Synergism
Yu, Shasha,Liu, Shenggao
supporting information, p. 381 - 385 (2018/01/27)
Multifunctional antioxidants with three active fragments were prepared through a simple two-step synthesis process. These novel compounds exhibited higher efficiency when inhibiting the oxidation of hydrocarbons compared to commercial products at 180 °C.
Bond dissociation energies of the N-H bond and rate constants for the reaction with alkyl, alkoxyl, and peroxyl radicals of phenothiazines and related compounds
Lucarini, Marco,Pedrielli, Pamela,Pedulli, Gian Franco,Valgimigli, Luca,Gigmes, Didier,Tordo, Paul
, p. 11546 - 11553 (2007/10/03)
The results of a detailed thermodynamic and kinetic investigation on the homolytic reactivity of phenothiazine, phenoxazine, and phenoselenazine, of several substituted phenothiazines, and of related tricyclic aromatic amines are reported. All these compo
KINETICS OF THE REACTION OF THE 2,4,6-TRI-TERT-BUTYLPHENOXYL RADICAL WITH AROMATIC AMINES UNDER QUASIEQUILIBRIUM CONDITIONS, AND THE DISSOCIATION ENERGY OF THE N-H BOND IN AROMATIC AMINES
Varlamov, V. T.,Denisov, E. T.
, p. 657 - 662 (2007/10/02)
We have studied the kinetics of the reaction of the 2,4,6-tri-tert butylphenoxyl radical with 11 aromatic amines under quasiequilibrium conditions.The equilibrium constant for each amine was determined from the kinetic results.These values, together with their temperature dependence, were used to calculate the dissociation energy of the N-H bond in the 11 aromatic amines.By using earlier results for the reaction of the aroxyl radical with cumyl hydroperoxide, catalyzed by aromatic amines, we have calculated the rate constants for the reaction of 10 aminyl radicals with cumyl hydroperoxide and of cumylperoxy radicals with 10 aromatic amines.