21459-32-5

Basic information

• Product Name: pentafluorophenylmercaptogold
• Synonyms: pentafluorophenylmercaptogold
• CAS NO: 21459-32-5
• Molecular Weight: 396.091
• Mol File: 21459-32-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pentafluorophenylmercaptogold(CAS DataBase Reference)
• NIST Chemistry Reference: pentafluorophenylmercaptogold(21459-32-5)
• EPA Substance Registry System: pentafluorophenylmercaptogold(21459-32-5)

Safety Data

• Hazardous Substances Data: 21459-32-5(Hazardous Substances Data)

Upstream product

• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 1076-44-4 pentafluorophenyl lithium 
• 392-56-3 Hexafluorobenzene 
• 50960-82-2 carbonylgold(I) chloride 
• 771-62-0 pentafluorophenylthiol 
• 20681-14-5 gold⁽¹⁺⁾ 

Downstream Products

• 7440-57-5 gold 

Relevant articles and documents

Reactions of Carbonylchlorogold(I) with Thiolates and Thiols. Crystal and Molecular Structures of t>, , 42 and 2 (L=1,4,7,10,13-pentaoxacyclopentadecane)

By the reaction of with the thiols RSH (R=But, C6H3Me2-2,6 or C6F5) amorphous gold(I) thiolates Au(SR) were obtained.With 2,6-dimethylbenzenethiolate under CO at atmospheric pressure in CH2Cl2 as solvent, gold metal and RSSR were formed, while with H2S amorphous Au2S was the product.The reaction of with t> in 1:1 ratio yielded t> 1 and 2 (15-crown-5=1,4,7,10,13-pentaoxacyclopentadecane).The crystal structure of 1 revealed that the anionic part contains three AuCl groups co-ordinated to the ButS- ligand forming a tetrahedral arrangement around the sulfur.The - anions in 2 are co-ordinated through the chlorine atoms to two + cations; thus, the sodium cation has a distorted pentagonal-pyramidal co-ordination to five oxygen atoms of the crown ether with the axial position occupied by the chlorine atoms of the AuCl2- anion.The reaction of with t> in 3:1 molar ratio afforded the mixed-valence AuI-AuIII complexes 42(Au4Cl6S2> 3 and 2 4.Their crystal structures revealed that in the 2- anion two AuCl2 units are connected by the sulfur atoms of two SAuCl groups forming a centrosymmetric planar Cl2Au(μ-S)2AuCl2 skeleton.The structure of 3 also contains linear - anions.