21514-24-9

Basic information

• Product Name: Benzenethiol, mercury(2+) salt
• CAS NO: 21514-24-9
• Molecular Formula: C6H6S.1/2Hg
• Molecular Weight: 418.933
• Mol File: 21514-24-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenethiol, mercury(2+) salt(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenethiol, mercury(2+) salt(21514-24-9)
• EPA Substance Registry System: Benzenethiol, mercury(2+) salt(21514-24-9)

Safety Data

• Hazardous Substances Data: 21514-24-9(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 1600-27-7 mercury(II) diacetate 
• 947751-06-6 ([2-mercapto-1-t-butylimidazole]HgEt)[BF₄] 
• 947751-02-2 [2-mercapto-1-t-butylimidazolyl]HgEt 
• 61640-27-5 2-mercapto-1-tert-butylimidazole 
• 882-33-7 diphenyldisulfane 
• 1095-04-1 triphenyl thiophosphite 
• 64-17-5 ethanol 
• 934-87-2 S-phenyl thioacetate 
• 12653-71-3 mercury(II) oxide 

Downstream Products

• 23528-44-1 1,2-bis-(phenylmercapto)ethylene 
• 13112-46-4 2,2-diphenyl-1-phenylthioethene 
• 99802-73-0 3,6-Bis-phenylsulfanyl-2,5,7-trithia-1,3,4,6-tetraphospha-bicyclo[2.2.1]heptane 
• 106371-06-6 acetato(benzenethiolato)mercury(II) 
• 1356918-52-9 (Hg(SC6H5)(μ-SC6H5)(μ-Cl)Ag(PC6H5)3)2)*dmf 
• 110903-75-8 {Hg₄(SC₆H₅)6(P(C₆H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)*1.5CHCl₃={Hg₄(SC₆H₅)6(P(C₆H₅)3)4}(ClO₄)2*1.5CHCl₃ 
• 110903-81-6 {Hg₄(SC₆H₅)6(P(C₂H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)={Hg₄(SC₆H₅)6(P(C₂H₅)3)4}(ClO₄)2 
• 110934-43-5 {Hg₄(SC₆H₅)6(As(C₆H₅)3)4}⁽²⁺⁾*2ClO₄^(1-)*1.5CHCl₃={Hg₄(SC₆H₅)6(As(C₆H₅)3)4}(ClO₄)2*1.5CHCl₃ 
• 3019-20-3 isopropylthiobenzene 
• 882-33-7 diphenyldisulfane 
• 16619-61-7 1-phenyl-2-phenylthioethene 

Relevant articles and documents

Synthesis of Thiol, Selenol, and Tellurol Esters by the Reaction of Organochalcogeno Mercurials with Acid Chlorides

Summary: Thiol, selenol, and tellurol esters were prepared by the reaction of bis(organochalcogeno)mercurials with acid chlorides in chloroform or carbon tetrachloride and in the presence of tetrabutylammonium halides as catalysts.

Phenylselenolate mercury alkyl compounds, PhSeHgMe and PhSeHgEt: Molecular structures, protolytic Hg-C bond cleavage and phenylselenolate exchange

The phenylselenolate mercury alkyl compounds, PhSeHgMe and PhSeHgEt, have been structurally characterized by X-ray diffraction, thereby demonstrating that both compounds are monomeric with approximately linear coordination geometries; the mercury centers do, nevertheless, exhibit secondary Hg...Se intermolecular interactions that serve to increase the coordination number in the solid state. The ethyl derivative, PhSeHgEt, undergoes facile protolytic cleavage of the Hg-C bond to release ethane at room temperature, whereas PhSeHgMe exhibits little reactivity under similar conditions. Interestingly, the cleavage of the Hg-C bond of PhSeHgEt is also more facile than that of the thiolate analog, PhSHgEt, which demonstrates that coordination by selenium promotes protolytic cleavage of the mercury-carbon bond. The phenylselenolate compounds PhSeHgR (R = Me, Et) also undergo degenerate exchange reactions with, for example, PhSHgR and RHgCl. In each case, the alkyl groups preserve coupling to the 199Hg nuclei, thereby indicating that the exchange process involves metathesis of the Hg-SePh/Hg-X groups rather than metathesis of the Hg-R/Hg-R groups.

Perfluoromethyl element ligands. XLI. [1] compounds of the type (F3C)2EE′R with pseudohalide character (E = P, As; E′ = S, Se, Te)

Perfluoromethyl phosphorus and -arsenic compounds of the type (F3C)2EE′R (E = P, As; E′ = S, Se, Te; R = organic group) are prepared either by dismutation (metathesis) of E2(CF3)4 with (RE′)2/su