215187-35-2Relevant articles and documents
Visible-light-photocatalyzed metal-free C-H heteroarylation of heteroarenes at room temperature: A sustainable synthesis of biheteroaryls
Maity, Pintu,Kundu, Debasish,Ranu, Brindaban C.
, p. 1727 - 1734 (2015)
An efficient C-H heteroarylation of heteroarenes is achieved through visible-light photoredox-catalyzed diazotization of heteroarylamines in situ by tBuONO at room temperature. A library of functionalized biheteroaryls is obtained by using this protocol.
Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides
Ge, Shaozhong,Hartwig, John F.
supporting information, p. 12837 - 12841 (2013/02/22)
One for all: The coupling of a range of nitrogen- and sulfur-containing heteroaryl halides with five-membered nitrogen-, oxygen-, and sulfur-containing heteroaryl boronic acids were achieved in high yields with only 0.5 mol % of the single-component nickel precatalyst [(dppf)NiCl(cinnamyl)] (dppf=1,1′- bis(diphenylphosphanyl)ferrocene). The reaction demonstrates good functional group compatibility, and is easily conducted on a large scale without a dry box. Copyright
Palladium/tris(tert-butyl)phosphine-catalyzed Suzuki cross-couplings in the presence of water
Lou, Sha,Fu, Gregory C.
supporting information; experimental part, p. 2081 - 2084 (2010/10/20)
Dipalladiumtris(dibenzylideneacetone)/tris(tert-butyl)phosphonium tetrafluoroborate/potassium fluoride dihydrate [Pd2(dba) 3/[HP(t-Bu)3]BF4/KF·2H2O] serves as a mild, robust, and user-friendly method for the efficient Suzuki cross-coupling of a diverse array of aryl and heteroaryl halides with aryl- and heteroarylboronic acids.
