215253-53-5

Basic information

• Product Name: Ag(SSi(OC(CH₃)3)3)(P(C₆H₅)3)2
• CAS NO: 215253-53-5
• Molecular Weight: 911.946
• Mol File: 215253-53-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ag(SSi(OC(CH₃)3)3)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ag(SSi(OC(CH₃)3)3)(P(C₆H₅)3)2(215253-53-5)
• EPA Substance Registry System: Ag(SSi(OC(CH₃)3)3)(P(C₆H₅)3)2(215253-53-5)

Safety Data

• Hazardous Substances Data: 215253-53-5(Hazardous Substances Data)

Upstream product

• 690-52-8 tri-tert-butoxysilanethiol 
• 603-35-0 triphenylphosphine 
• 101701-30-8 Ag⁽¹⁺⁾*SSi(OC(CH₃)3)3^(1-) = AgSSi(OC(CH₃)3)3 

Relevant articles and documents

Synthesis, X-ray and solid state NMR studies on silver(I) silanethiolates. Crystal structure of bis[(triphenylphosphine)-(tri-o-tolylsilanethiolato)silver(I)]-toluene(1/2), [{Ag[SSi(C6H4-Me-o)3](PPh3)} 2]·2C6H5Me

A series of silver(I) trialkoxysilanethiolates [Ag(SSiR3)(PPh3)2], R = ButO, BusO or PriO, and triarylsilanethiolates [Ag(SSiR′3)(PPh3)], R′ = o-MeC6H4 or Ph, were obtained by reaction of [Ag(acac)(PPh3)2] with the respective silanethiols. Products were studied by 1H NMR, CP MAS 31P and 29Si NMR in solution and/or in the solid state. A single-crystal X-ray structural analysis was carried on for [{Ag[SSi(C6H4Me-o)3](PPh3)} 2]·2C6H5Me.