21592-62-1Relevant articles and documents
Regioselective formation of cyclic and allylic hydroperoxides
Stratakis,Orfanopoulos
, p. 425 - 430 (1993)
A regioselective photosensitized oxygenation is reported for the preparation of cyclic and allylic hydroperoxides.
Palladium-Catalyzed Asymmetric Allylic Fluoroalkylation/Trifluoromethylation
Trost, Barry M.,Gholami, Hadi,Zell, Daniel
supporting information, p. 11446 - 11451 (2019/08/20)
The first palladium-catalyzed asymmetric allylic trifluoromethylation is disclosed. The methodology evokes a fundamental principle by which the synergistic interplay of a leaving group and its subsequent activation of the nucleophilic trifluoromethyl grou
Addition of hypobromous acid to 1-phenylcycloalkenes
Ceylan,Findik,Sahin,Kazaz
, p. 2299 - 2303 (2014/05/06)
Reaction of 1-phenylcyclooctene and 1-phenylcycloheptene with N-bromosuccinimide (NBS) in aqueous DMSO gives the corresponding 3-bromo-2-phenylcycloalkenes and 2-phenylcycloalk-2-enols in a ratio of 3: 1. Unlike them, 1-phenylcyclohexene gives a mixture of 3-bromo-2-phenylcyclohexene and 2-bromo-1-phenylcyclohexanol. The oxidation of allylic alcohols with pyridinium chlorochromate afforded the corresponding α,β-unsaturated ketones.