215929-10-5

Basic information

• Product Name: (1R,3S,4R,5R)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydroxy-2-oxo-cyclohexanecarboxylic acid methyl ester
• Synonyms: (1R,3S,4R,5R)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydroxy-2-oxo-cyclohexanecarboxylic acid methyl ester
• CAS NO: 215929-10-5
• Molecular Weight: 376.479
• Mol File: 215929-10-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,3S,4R,5R)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydroxy-2-oxo-cyclohexanecarboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3S,4R,5R)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydroxy-2-oxo-cyclohexanecarboxylic acid methyl ester(215929-10-5)
• EPA Substance Registry System: (1R,3S,4R,5R)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydroxy-2-oxo-cyclohexanecarboxylic acid methyl ester(215929-10-5)

Safety Data

• Hazardous Substances Data: 215929-10-5(Hazardous Substances Data)

Upstream product

• 215929-08-1 (1R,4S,4aR,6R,8R,8aS)-6-Acetoxy-8-(tert-butyl-dimethyl-silanyloxy)-5-oxo-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalene-6-carboxylic acid methyl ester 
• 215929-07-0 (1R,4S,4aR,6R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-6-hydroxy-5-oxo-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalene-6-carboxylic acid methyl ester 
• 215929-06-9 (1R,4S,4aR,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-1,4,4a,7,8,8a-hexahydro-1,4-methano-naphthalene-6-carboxylic acid methyl ester 
• 171824-23-0 (-)-(1S,4R,4aS,5R,8aR)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8a-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one 
• 215929-09-2 (1R,5R)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohex-3-enecarboxylic acid methyl ester 

Downstream Products

• 191916-39-9 methyl (-)-quinate 
• 40983-58-2 methyl shikimate 
• 77-95-2 D-(-)-quinic acid 
• 138-59-0 shikimic acid 

Relevant articles and documents

A concise enantio- and diastereo-controlled synthesis of (-)-quinic acid and (-)-shikimic acid

(-)-Quinic acid and (-)-shikimic acid, both recognized as the key intermediates in the shikimate pathway in plants and microorganisms, have been synthesized concisely in an enantio- and diastereo-controlled manner starting from a synthetic equivalent of (R)-4-hydroxycyclohex-2-enone.