216663-82-0

Basic information

• Product Name: (R)-1-bromo-3-(1'-methoxyethyl)benzene
• Synonyms: (R)-1-bromo-3-(1'-methoxyethyl)benzene
• CAS NO: 216663-82-0
• Molecular Weight: 215.09
• Mol File: 216663-82-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-1-bromo-3-(1'-methoxyethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-bromo-3-(1'-methoxyethyl)benzene(216663-82-0)
• EPA Substance Registry System: (R)-1-bromo-3-(1'-methoxyethyl)benzene(216663-82-0)

Safety Data

• Hazardous Substances Data: 216663-82-0(Hazardous Substances Data)

Upstream product

• 2142-63-4 1-(3-Bromophenyl)ethanone 
• 52780-14-0 (R)-1-(3-bromophenyl)ethanol 
• 74-88-4 methyl iodide 

Relevant articles and documents

Optically active C3-symmetric triarylphosphines in asymmetric allylations

A new class of optically active, monodentate, C3-symmetric ligands for asymmetric catalysis, 1-3, were prepared via routes involving asymmetric reduction of aryl ketones (Schemes 1-3). Single crystal X-ray structures of trans-PdCl2(phosphine)2 complexes of ligands 1a, 2a and 3a showed that the ligands do not adopt perfect C3-symmetric conformations in the solid state; in fact, all three have one aromatic ring lying 'face-on' to the metal. Circular dichroism studies of the same complexes provided some evidence for an aromatic ordering effect for complex 22, but none for 21 and 23. Palladium catalyzed allylation reactions using ligands 1-3 showed that encouraging enantioselectivities could be obtained, particularly for cyclic, allylic substrates.