21686-93-1Relevant articles and documents
Lewis adducts of the Fe(CO)42- and Co(CO)4- ions
Ruff
, p. 1499 - 1503 (2008/10/08)
The metal carbonyl anions Fe(CO)42- and Co(CO)4- form adducts with indium tribromide or gallium tribromide of the type M(CO)4M′Br3n-. The complex ion Fe(CO)4InBr32- dissociates in solution to give a new ion Fe(CO)4InBr2-. This new ion will form adducts with amines and the preparation of the ions Fe(CO)4InBr2·(C2H5) 3N- and Fe(CO)4InBr2·C5H5N - is also described.