21713-52-0Relevant articles and documents
Electrochemical Enabled Cascade Phosphorylation of N?H/O?H/S?H Bonds with P?H Compounds: An Efficient Access to P(O)-X Bonds
Abdukader, Ablimit,Dong, Xiaojuan,Jin, Weiwei,Liu, Chenjiang,Wang, Bin,Wang, Ruige,Xia, Yu,Xue, Fei,Zhang, Yonghong
supporting information, p. 14931 - 14935 (2021/10/06)
An electrochemical three component cascade phosphorylation reaction of various heteroatoms-containing nucleophiles including carbazoles, indoles, phenols, alcohols, and thiols with Ph2PH has been established. Electricity is used as the “traceless” oxidant and water and air are utilized as the “green” oxygen source. All kinds of structurally diverse organophosphorus compounds with P(O)-N/P(O)-O/P(O)-S bonds are assembled in moderate to excellent yields (three categories of phosphorylation products, 50 examples, up to 97 % yield). A tentative free radical course is put forward to rationalize the reaction procedure.
Phosphonate compound, preparation method and application thereof
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Paragraph 0059-0061, (2020/04/02)
The invention provides a phosphonate compound, a preparation method and application thereof. The method includes the steps of: in a nitrogen atmosphere, mixing a P(O)-H compound, an aryl trifluoromethanesulfonate compound, an alkali reagent and an organic solvent, carrying out stirring reaction at 80-130DEG C for 15-24h, and conducting cooling, washing and extraction at the end of reaction to obtain an organic phase; drying and distilling the obtained organic phase to obtain the phosphonate compound; wherein the molar ratio of the P(O)-H compound, the aryl trifluoromethanesulfonate compound and the alkali reagent is 1-3:1:2-3. The method has the advantages of simple and easily available raw materials, simple reaction conditions, wide functional group compatibility, high yield and wide applicability, the structural formula of the obtained phosphonate compound is shown as formula (I) in the specification, and the extraction rate of the phosphonate compound applied to the field of lithiumion extraction is 53% or above.
Method for preparing organophosphate compound through efficient esterification of P(O)-OH-containing compound and phenol
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Paragraph 0034, (2017/09/01)
The invention provides a method for preparing an organophosphate compound through efficient esterification of a P(O)-OH-containing compound and phenol. The method realizes efficient and highly selective synthesis of organophosphate derivatives containing