217479-61-3

Basic information

• Product Name: 2,4,6-trichlorobenzyl bromide
• Synonyms: 2,4,6-trichlorobenzyl bromide
• CAS NO: 217479-61-3
• Molecular Weight: 274.372
• Mol File: 217479-61-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,4,6-trichlorobenzyl bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-trichlorobenzyl bromide(217479-61-3)
• EPA Substance Registry System: 2,4,6-trichlorobenzyl bromide(217479-61-3)

Safety Data

• Hazardous Substances Data: 217479-61-3(Hazardous Substances Data)

Upstream product

• 50-43-1 2,4,6-trichlorobenzoic acid 
• 217479-60-2 (2,4,6-trichlorophenyl)methanol 
• 23749-65-7 2,4,6-trichlorotoluene 

Downstream Products

• 1435476-00-8 C₁₀H₆Cl₃F₃O₃ 
• 1435476-01-9 C₁₀H₅Cl₄F₃O₂ 
• 1435475-86-7 C₁₃H₉Cl₃F₃N₃O₃ 
• 1435475-99-2 C₉H₆Cl₃F₃O 
• 24473-00-5 2,4,6-trichlorobenzaldehyde 
• 217479-60-2 (2,4,6-trichlorophenyl)methanol 
• 736170-21-1 N-methoxy-N-methyl-4-(2,4,6-trichloro-benzyloxy)-butyramide 

Relevant articles and documents

Preparation method of 2, 4, 6-trichlorophenyl substituted acetone

The invention relates to a preparation method of 2, 4, 6-trichlorophenyl substituted acetone, which comprises the following steps: adding 2, 4, 6-trichlorotoluene and a chlorination reagent into an organic solvent at a certain temperature to prepare 2, 4, 6-trichlorophenyl benzyl chloride, then coupling with ethynyl magnesium halide under the action of a metal catalyst, and then carrying out acid catalysis and water addition to finally obtain the product 2, 4, 6-trichlorophenyl substituted acetone. The method provided by the invention has the advantages of many raw material sources, obvious cost advantage, safer and more convenient preparation method, high total yield and less three wastes, and is beneficial to industrialization.

Kinetic studies on the interactions of manganese-porphyrins with peracetic acid. Part 1. Epoxidation of alkenes and hydroxylation of aromatic rings

The mechanism of peracetic acid interactions with MnIII complexes of meso-tetra(2,6-dichloro-4-R-phenyl)-porphyrins (RTDCPPMnCl; R = CH3O, H, Br, Cl or NO2) in acetonitrile-acetic acid has been studied. Analysis of the kinetic data revealed that both in cis-stilbene epoxidation and naphthalene hydroxylation the first step of the reaction is the reversible formation of an intermediate adduct 'A' between the catalyst and the oxidant. The subsequent irreversible transformation of 'A' with rate constant k2 leads to the formation of two high-valent oxometallo species, [RTDCPPMnV(O)] and supposedly [RTDCPPMnIV(O)]+. These species are in equilibrium and show distinct oxidation abilities towards the substrates.