217662-69-6

Basic information

• Product Name: 2,6-dibromo-N,N'-bis(trimethylsilyl)aniline
• Synonyms: 2,6-dibromo-N,N'-bis(trimethylsilyl)aniline
• CAS NO: 217662-69-6
• Molecular Weight: 395.284
• Mol File: 217662-69-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,6-dibromo-N,N'-bis(trimethylsilyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-dibromo-N,N'-bis(trimethylsilyl)aniline(217662-69-6)
• EPA Substance Registry System: 2,6-dibromo-N,N'-bis(trimethylsilyl)aniline(217662-69-6)

Safety Data

• Hazardous Substances Data: 217662-69-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 608-30-0 2,6-dibromoaniline 
• 1159339-39-5 2,6-dibromo-N-(trimethylsilyl)aniline 

Downstream Products

• 1159339-45-3 2-bromo-6-(trimethylsilyl)aniline 
• 1159339-47-5 2-bromo-6-trimethylsilyl-N-(trimethylsilyl)aniline 
• 217662-70-9 2-bromo-6-trimethylsilyl-N,N-bis(trimethylsilyl)aniline 

Relevant articles and documents

Synthesis of N-and C-trimethylsilyl-substituded anililes

N-Metallation of bromoanilines with ethylmagnesium bromide followed by a reaction with trimethylchlorosilane provided N-mono and N-bis(trimethylsilyl) bromoanilines depending on the structure of substrate. The metallation of bissilylated bromoanilines with butyllithium permitted the introduction of a trimethylsilyl substituent in the aromatic ring. Previously unknown 2-bromo-N,N-bis(trimethylsilyl)aniline, 2,6-dibromo-N-trimethylsilylaniline, 2,6-dibromo-N,N-bis(trimethylsilyl)aniline, 2-bromo-6-trimethylsilylaniline, 2-bromo-6-trimethylsilyl-N,N-bis(trimethylsilyl)aniline, 2-bromo-6- trimethylsilyl-N-trimethylsilylaniline, 2,4,6-tribromo-N-trimethylsilylaniline, and 2,4,6-tribromo-N,N-bis(trimethylsilyl)aniline were prepared. The structures of the compounds obtained were established by the chromato-mass spectrometry and 1H, 13C, and 29Si NMR spectroscopy.