2186-93-8Relevant articles and documents
Highly efficient acetalization of carbonyl compounds catalyzed by anilin-aldehyde resin salts
Tanemura, Kiyoshi,Suzuki, Tsuneo
supporting information, p. 797 - 799 (2015/06/22)
A mild procedures for the syntheses of ethylene acetals and dimethyl acetals from the corresponding aldehydes and ketones catalyzed by 1mol% of anilinealdehyde resin salts are described. This method is also useful for the synthesis of dimethyl acetals of diaryl ketones.
Synthesis of D-erythro-sphinganine through serine-derived α-amino epoxides
Siciliano, Carlo,Barattucci, Anna,Bonaccorsi, Paola,Di Gioia, Maria Luisa,Leggio, Antonella,Minuti, Lucio,Romio, Emanuela,Temperini, Andrea
, p. 5320 - 5326 (2014/06/23)
A total synthesis of d-erythro-sphinganine [(2S,3R)-2-aminooctadecane-1,3- diol] starting from commercial N-tert-butyloxycarbonyl-l-serine methyl ester is described. The approach is based on the completely stereoselective preparation of an α-amino epoxide obtained by treating a protected l-serinal derivative with dimethylsulfoxonium methylide. The oxirane synthon is obtained with an anti configuration fitting the (2S,3R) stereochemistry of the 2-amino-1,3-diol polar head of d-erythro-sphinganine. The synthetic procedure afforded the target compound in a 68% overall yield based on the initial amount of the starting l-serine material.
Iron(III) tosylate in the preparation of dimethyl and diethyl acetals from ketones and β-keto enol ethers from cyclic β-diketones
Mansilla, Horacio,Afonso, Maria M.
, p. 2607 - 2618 (2008/12/22)
An efficient method for conversion of ketones to their corresponding dimethyl and diethyl acetals and of cyclic β-diketones into β-keto enol ethers using Fe(OTs)3 as a catalyst is described. Copyright Taylor & Francis Group, LLC.