218628-92-3Relevant articles and documents
Nucleophilic substitutions on Multipin systems linked with a traceless linker
Takahashi, Takashi,Tomida, Satoshi,Inoue, Hitoshi,Doi, Takayuki
, p. 1261 - 1263 (2007/10/03)
The displacement of polymer-supported glucose 7 at the 6-position by azide, iodide, and acetate was achieved through a 4-hydroxybenzenesulfonate-linked Multipin system giving the corresponding glucose derivatives 8 in excellent yields. Macrocyclization of polymer-supported cyanohydrin ether 13 by displacement of the traceless sulfonate linker provided the cyclic compound 14 in moderate yield but in pure form.