218794-73-1

Basic information

• Product Name: [OsHCl(CS)(C₆H₄N₂S)(P(C₆H₅)3)2]
• CAS NO: 218794-73-1
• Molecular Weight: 931.497
• Mol File: 218794-73-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [OsHCl(CS)(C₆H₄N₂S)(P(C₆H₅)3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [OsHCl(CS)(C₆H₄N₂S)(P(C₆H₅)3)2](218794-73-1)
• EPA Substance Registry System: [OsHCl(CS)(C₆H₄N₂S)(P(C₆H₅)3)2](218794-73-1)

Safety Data

• Hazardous Substances Data: 218794-73-1(Hazardous Substances Data)

Upstream product

• 273-13-2 benzo[1,2,5]thiadiazole 
• 218795-12-1 OsH(CS)(NCCH₃)2(P(C₆H₅)3)2⁽¹⁺⁾*ClO₄^(1-) = [OsH(CS)(NCCH₃)2(P(C₆H₅)3)2]ClO₄ 
• 56-34-8 tetraethylammonium chloride 

Downstream Products

• 218794-91-3 [OsCl(CS)(CHCHC₆H₄CH₃)(C₆H₄N₂S)(P(C₆H₅)3)2] 

Relevant articles and documents

Alkenyl and alkynyl complexes of osmium(II) derived from [OsH(Cl)(CO)(BTD)(PPh3)2] (BTD = 2,1,3-benzothiadiazole)

Treatment of [OsH(CA)(NCMe)2(PPh3)2]+ (A = O or S) with [NEt4]Cl and 2,1,3-benzothiadiazole (BTD) provided [OsH(Cl)(CA)(BTD)(PPh3)2] (A = O or S). Under mild conditions, the complex [OsH(Cl)(CO)(BTD)(PPh3)2] hydro-osmiates ethynyltoluene, ethyne and di(4-tolyl)butadiyne to provide vinyl complexes [Os(CH=CHR)Cl(CO)(BTD)-(PPh3)2] (R = C6H4Me-4), [Os(CH=CH2)Cl(CO)(BTD)(PPh3)2] and [Os{C(C≡CR)≡CHR}Cl(CO)(BTD)(PPh3)2]. Complex [OsH(CO)(NCMe)2(PPh3)2]+ reacted with HC≡CR to provide [Os(CH=CHR)(CO)(NCMe)2(PPh3)2]+ which is converted by [NEt4]Cl into [Os(CH=CHR)Cl(CO)(NCMe)(PPh3)2]. Treatment of [Os(CH=CHR)Cl(CO)-(BTD)(PPh3)2] with CNCMe3 or CO provided [Os(CH=CHR)Cl(CO)(L)(PPh3)2] (L = CNCMe3 or CO). The dithiocarbamate complex [Os(CH=CHR)(S2CNMe2)(CO)(PPh3)2] and the osmatetraborane [Os(CH=CHR)-(B3H8)(CO)(PPh3)2] resulted from the reactions of [Os(CH=CHR)Cl(CO)(BTD)(PPh3)2] with Na[S2CNMe2] and [NBun4][B3H8], respectively, whereas with K[HB(pz)3] (pz = pyrazolyl) initially [Os(CH=CHR)(CO)(PPh3)2-{η2-HB(pz) 3}] was formed which is converted into [Os(CH=CHR)(CO)(PPh3){HB(pz)3}] on heating. No intermediates are however observed in the corresponding reaction with 1,4,7-trithiacyclononane ([9]aneS3) to provide [Os(CH=CHR)(CO)(PPh3)([9]aneS3)]+. The alkynyl complex [Os(C≡CR)Cl(CO)(BTD)(PPh3)2] was obtained from either (i) the reaction of [OsH(Cl)(CO)(BTD)(PPh3)2] with [Hg(C≡CR)2] or (ii) [Os(CH=CHR)Cl(CO)(BTD)(PPh3)2] with an excess of HC≡CR. Treatment of [Os(C≡CR)Cl(CO)(BTD)(PPh3)2] with Na[S2CNMe2] or alternatively [Os(CH=CHR)(S2CNMe2)(CO)(PPh3)2] with an excess of HC≡CR provided [Os(C≡CR)(S2CNMe2)(CO)(PPh3) 2], which can also be obtained from [OsH(S2CNMe2)(CO)(PPh3)2] and [Hg(C≡CR)2]. The BTD in [Os(OCR)Cl(CO)-(BTD)(PPh3)2] is substituted by CNCMe3 to provide [Os(C≡CR)Cl(CO)(CNCMe3)(PPh3)2]. The reaction of [OsH(Cl)(CS)(BTD)(PPh3)2] with HC≡CR provided [Os(CH=CHR)Cl(CS)(BTD)(PPh3)2] which in contrast to [Os(CH=CHR)Cl(CO)(BTD)(PPh3)2] reacts with carbon monoxide to provide the thiocinnamoyl complex [Os(η2-SCCH=CHR)Cl(CO)(PPh3)2].