219581-98-3

Basic information

• Product Name: (1S)-Methyl-1-[2-(E)-phenylethenyl]-2,2-diphenylcyclopropane-1-carboxylate
• Synonyms: (1S)-Methyl-1-[2-(E)-phenylethenyl]-2,2-diphenylcyclopropane-1-carboxylate
• CAS NO: 219581-98-3
• Molecular Weight: 354.448
• Mol File: 219581-98-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S)-Methyl-1-[2-(E)-phenylethenyl]-2,2-diphenylcyclopropane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-Methyl-1-[2-(E)-phenylethenyl]-2,2-diphenylcyclopropane-1-carboxylate(219581-98-3)
• EPA Substance Registry System: (1S)-Methyl-1-[2-(E)-phenylethenyl]-2,2-diphenylcyclopropane-1-carboxylate(219581-98-3)

Safety Data

• Hazardous Substances Data: 219581-98-3(Hazardous Substances Data)

Upstream product

• 530-48-3 1,1-Diphenylethylene 
• 119987-21-2 (E)-methyl 2-diazo-4-phenylbut-3-enoate 

Downstream Products

• 219581-99-4 (1S)-Methyl-1-{N-[(1,1-dimethylethyl)oxycarbonyl]amino}-2,2-diphenylcyclopropane-1-carboxylate 
• 249648-52-0 (1S)-1-{N-[(1,1-Dimethylethyl)oxycarbonyl]amino}-2,2-diphenylcyclopropane-1-N'-(methylethyl)carboxamide 
• 219582-00-0 (1S)-1-{N-[(1,1-Dimethylethyl)oxycarbonyl]amino}-2,2-diphenylcyclopropane-1-carboxylic acid 

Relevant articles and documents

Asymmetric synthesis of 3-phenyl-2,3-methanophenylalanine developed by panning catalysts in a library format

Optimal catalysts for the key cyclopropanation step in a synthesis of the title compound were identified by screening libraries of metal complex-ligand combinations; the synthesis was completed, and a derivative of the final product was crystallized to es

Novel dirhodium tetraprolinate catalysts containing bridging prolinate ligands for asymmetric carbenoid reactions

The D2-symmetric dirhodium prolinate complex 3 is an effective catalyst for asymmetric vinylcarbenoid and phenylcarbenoid cyclopropanations.