219679-04-6

Basic information

• Product Name: 5-bromo-2-(2-iodophenyl)pentanenitrile
• Synonyms: 5-bromo-2-(2-iodophenyl)pentanenitrile
• CAS NO: 219679-04-6
• Molecular Weight: 364.024
• Mol File: 219679-04-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-bromo-2-(2-iodophenyl)pentanenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 5-bromo-2-(2-iodophenyl)pentanenitrile(219679-04-6)
• EPA Substance Registry System: 5-bromo-2-(2-iodophenyl)pentanenitrile(219679-04-6)

Safety Data

• Hazardous Substances Data: 219679-04-6(Hazardous Substances Data)

Upstream product

• 40400-15-5 2-(2-iodophenyl)acetonitrile 
• 109-64-8 1,3-dibromo-propane 

Downstream Products

• 1151654-21-5 1-(2-iodophenyl)cyclobutanecarbonitrile 

Relevant articles and documents

Studies in Acyl C-H activation via aryl and alkyl to acyl "through space" migration of palladium

Examples of the 1,4-migration of a palladium moiety in aryl- and alkylpalladium intermediates to the acyl position of an aldehyde or formamide have been observed. The resulting acylpalladium intermediate can undergo ester or carbamate formation by reaction with an alcohol; decarbonylation, followed by β hydride elimination to an alkene; reaction with an organomercurial to form an ester; or alkene insertion. Deuterium-labeling studies have been used to confirm the palladium migration mechanism.