219753-93-2

Basic information

• Product Name: di-tert-butyl 1-(4-methoxyphenyl)hydrazine-1,2-dicarboxylate
• Synonyms: di-tert-butyl 1-(4-methoxyphenyl)hydrazine-1,2-dicarboxylate
• CAS NO: 219753-93-2
• Molecular Weight: 338.404
• Mol File: 219753-93-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: di-tert-butyl 1-(4-methoxyphenyl)hydrazine-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: di-tert-butyl 1-(4-methoxyphenyl)hydrazine-1,2-dicarboxylate(219753-93-2)
• EPA Substance Registry System: di-tert-butyl 1-(4-methoxyphenyl)hydrazine-1,2-dicarboxylate(219753-93-2)

Safety Data

• Hazardous Substances Data: 219753-93-2(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 16466-61-8 1,2-bis(t-butyloxycarbonyl)hydrazine 
• 696-62-8 para-iodoanisole 
• 870-50-8 di-tert-butyl-diazodicarboxylate 
• 5720-07-0 4-methoxyphenylboronic acid 
• 213596-33-9 2-(4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborolane 
• 623-12-1 4-chloromethoxybenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 870-50-8 di-tert-butyl (E)-azodicarboxylate 
• 870-46-2 t-butoxycarbonylhydrazine 

Relevant articles and documents

Amination of Arylboronic Compounds via the Copper-Catalyzed Addition of Arylboronic Esters to Azodicarboxylates

Arylboronic esters add to di-tert-butyl azodicarboxylate under mild reaction conditions (at room temperature) to afford aryl-substituted hydrazine derivatives in good yields. The reaction tolerates a wide variety of functional groups.

Cp?Rh(III)-catalyzed electrophilic amination of arylboronic acids with azo compounds for synthesis of arylhydrazides

A [Cp?Rh(iii)]-catalyzed electrophilic amination of arylboronic acids with diethyl azodicarboxylate (DEAD) was developed, and arylhydrazides were produced in excellent yields and selectivity. The analogous amination with the arylazocarboxylates afforded t

Copper salt catalyzed addition of arylboronic acids to azodicarboxylates

The addition of arylboronic acids 1 to azodicarboxylates 2 in the presence of a catalytic amount of a copper salt under mild reaction conditions gives aryl-substituted hydrazines 3 in high yields. The reaction is tolerant of a wide variety of functional groups.