22005-33-0

Basic information

• Product Name: piperazine-1,4-dicarbonitrile
• Synonyms: piperazine-1,4-dicarbonitrile;1,4-Piperazinedicarbonitrile;Einecs 244-713-7
• CAS NO: 22005-33-0
• Molecular Formula: C₆H₈N₄
• Molecular Weight: 136.15452
• EINECS: 244-713-7
• Mol File: 22005-33-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 423.1 °C at 760 mmHg
• Flash Point: 213.6 °C
• Appearance: /
• Density: 1.23 g/cm³
• Vapor Pressure: 2.3E-07mmHg at 25°C
• Refractive Index: 1.555
• CAS DataBase Reference: piperazine-1,4-dicarbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: piperazine-1,4-dicarbonitrile(22005-33-0)
• EPA Substance Registry System: piperazine-1,4-dicarbonitrile(22005-33-0)

Safety Data

• Hazardous Substances Data: 22005-33-0(Hazardous Substances Data)

Usage

General Description

Piperazine-1,4-dicarbonitrile is a chemical compound that consists of a six-membered ring containing two nitrogen atoms and two carbon atoms, with each carbon atom bearing a nitrile functional group. It is commonly used as a building block in the synthesis of various pharmaceuticals and organic compounds. Piperazine-1,4-dicarbonitrile exhibits high reactivity and is known for its ability to undergo various chemical transformations, making it a versatile intermediate in the production of a wide range of organic molecules. Its unique structure and reactivity make it a valuable compound in the field of organic chemistry, with potential applications in drug development and materials science.

InChI:InChI=1/C6H8N4/c7-5-9-1-2-10(6-8)4-3-9/h1-4H2

Upstream product

• 110-85-0 piperazine 
• 506-68-3 bromocyane 

Downstream Products

• 128118-77-4 6-chloro-2-(4-cyanohexahydropyrazin-1-yl)-4-oxo-5-phenyl-4H-1,3-oxazine 
• 128118-74-1 C₂₄H₁₈Cl₂N₄O₄ 
• 90234-85-8 N,N'-Bis(phenylglyoxyloyl)-1,4-piperazin-bis(carboximidoylchlorid) 
• 90234-80-3 N,N'-Bis(4-nitrobenzoyl)-1,4-piperazin-bis(carboximidoylchlorid) 
• 110-85-0 piperazine 
• 7664-41-7 ammonia 
• 90235-14-6 N,N''-Dicyclohexyl-N'N'''-bis(trichloracetyl)-1,4-piperazindi(carboxamidin) 
• 90234-97-2 N,N'-Bis(trichloracetyl)-1,4-piperazin-bis(carboximidsaeure-phenylester) 
• 90235-03-3 N,N'-Bis(trichloracetyl)-1,4-piperazinbis(thiocarboximidsaeure-p-tolylester) 
• 90235-18-0 N,N''-Di-p-tolyl-N',N'''-bis(trichloracetyl)-1,4-piperazindi(carboxamidin) 
• 90235-19-1 N,N''-Bis(4-chlorphenyl)-N',N'''-bis(trichloracetyl)-1,4-piperazindi(carboxamidin) 
• 90234-98-3 N,N'-Bis(trichloracetyl)-1,4-piperazin-bis(carboximidsaeure-2-chlorphenylester) 
• 90235-04-4 N,N'-Bis(trichloracetyl)-1,4-piperazinbis(thiocarboximidsaeure-2-chlorphenylester) 
• 90234-99-4 N,N'-Bis(trichloracetyl)-1,4-piperazin-bis(carboximidsaeure-2,4,6-trichlorphenylester) 

Relevant articles and documents

2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior

Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min?1. The best result was obtained for compound4, which can be correlated to its largest lattice volume.