22007-82-5Relevant articles and documents
Hypervalent iodine in synthesis XXXI: Formation of phosphinimines and arsinimines by nitrene route or non-nitrene route
Ou, Wei,Wang, Zhi-Gang,Chen, Zhen-Chu
, p. 2301 - 2309 (2007/10/03)
N-sulfonyltriphenylphosphinimines and N-sulfonyltriphenylarsinimines are prepared by the reaction of triphenylphosphine or triphenylarsine under nitrene-producing conditions with I-N ylide (PhI=NSO2R). Triphenylarsinimines can also be generated by a non-nitrene route from triphenylarsine, iodobenzene diacetate, and sulfonamides via triphenylarsine diacetate, Ph3As(OAc)2.