220098-86-2

Basic information

• Product Name: [C₆H₅P(C₅(CH₃)4)2]TiCl₂
• CAS NO: 220098-86-2
• Molecular Weight: 467.254
• Mol File: 220098-86-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [C₆H₅P(C₅(CH₃)4)2]TiCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: [C₆H₅P(C₅(CH₃)4)2]TiCl₂(220098-86-2)
• EPA Substance Registry System: [C₆H₅P(C₅(CH₃)4)2]TiCl₂(220098-86-2)

Safety Data

• Hazardous Substances Data: 220098-86-2(Hazardous Substances Data)

Upstream product

• 31011-57-1 tetrachlorobis(tetrahydrofuran)titanium(IV) 

Downstream Products

• 220098-87-3 [C₆H₅P(C₅(CH₃)4)2]Ti(CH₃)2 

Relevant articles and documents

Phosphorus-bridged ansa-metallocene complexes of titanium, zirconium, and hafnium: The syntheses and structures of [PhP(C5Me4)2]MX2 and [Ph(E)P(C5Me4)2]MX2 (E = O, S, Se) derivatives

A series of phosphorus-bridged ansa-metallocene complexes of titanium, zirconium, and hafnium, [PhP(C5Me4)2]MX2 and [Ph(E)P(C5Me4)2]MX2 (X = Cl, Me, CO, (Se3)0.5, (Te3)0.5; E = O, S, Se), has been synthesized. Structural characterization by X-ray diffraction indicates that, in comparison to their non-ansa counterparts (C5Me5)2MX2, the cyclopentadienyl groups in phosphorus-bridged complexes are displaced from symmetric η5-coordination toward η3-coordination. Such η3,η3-coordination creates more electrophilic metal centers than those in their permethylcyclopentadienyl counterparts, as judged by the v(CO) stretching frequencies of the zirconium dicarbonyl complexes Cp*2Zr(CO)2 (1946 and 1853 cm-1) and [PhP(C5Me4)2]Zr(CO)2 (1959 and 1874 cm-1).