220263-61-6

Basic information

• Product Name: (R_S)-2-methyl-N-(1-phenylpentylidene)propane-2-sulfinamide
• Synonyms: (R_S)-2-methyl-N-(1-phenylpentylidene)propane-2-sulfinamide
• CAS NO: 220263-61-6
• Molecular Weight: 265.42
• Mol File: 220263-61-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R_S)-2-methyl-N-(1-phenylpentylidene)propane-2-sulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: (R_S)-2-methyl-N-(1-phenylpentylidene)propane-2-sulfinamide(220263-61-6)
• EPA Substance Registry System: (R_S)-2-methyl-N-(1-phenylpentylidene)propane-2-sulfinamide(220263-61-6)

Safety Data

• Hazardous Substances Data: 220263-61-6(Hazardous Substances Data)

Upstream product

• 1009-14-9 phenyl butyl ketone 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 

Relevant articles and documents

Reversal of diastereofacial selectivity in hydride reductions of N-tert-butanesulfinyl imines

A variety of N-tert-butanesulfinyl imines were reduced with NaBH 4 in THF containing 2% water to provide the corresponding secondary sulfinamides in high yield and diastereoselectivity. By using the same sulfinyl imine starting materials and changing the reductant to L-Selectride, the stereoselectivity could be efficiently reversed to afford the opposite product diastereomer in high yield and selectivity.