22031-15-8Relevant articles and documents
Homogeneous Catalytic Hydrogenation of CO2 to Methanol – Improvements with Tailored Ligands
Scharnagl, Florian Korbinian,Hertrich, Maximilian Franz,Neitzel, Gordon,Jackstell, Ralf,Beller, Matthias
, p. 374 - 379 (2019/01/04)
Improved molecularly-defined cobalt catalysts for the hydrogenation of carbon dioxide to methanol have been developed. A key factor for increased productivity (up to twofold compared to previous state-of-the-art-system) is the specific nature of substitue
Eine einfache Synthese von Tripod-Liganden H3CC(CH2PAr2)3: Anwendungsbreite und Komplexchemie
Muth, A.,Walter, O.,Huttner, G.,Asam, A.,Zsolnai, L.,Emmerich, Ch.
, p. 149 - 164 (2007/10/02)
The reaction of 1,1,1-tris(chlormethyl)ethane H3CC(CH2Cl)3 with Ar2PH in DMSO as the solvent using KOH/H2O as the base gives good yields of tripod ligands H3CC(CH2PAr2)3, 2.Using Ph2PH as the phosphine component, it is shown that the chloride substituents