220446-69-5Relevant articles and documents
Synthesis of 5-phenyl 2-functionalized pyrroles by amino Heck and Tandem amino Heck carbonylation reactions
Zaman, Shazia,Kitamura, Mitsuru,Abell, Andrew D.
, p. 624 - 626 (2008/03/12)
2-Methyl-, 2-(methoxycarbonyl)methyl-, and 2,2-[(ethoxycarbonyl) (methoxycarbonyl)]methyl-5-phenylpyrroles are prepared from the corresponding 3-butynyl and 4-(methoxycarbonyl)-3-butynyl phenyl ketone O-pentafluorobenzoyl oximes by amino Heck cyclization
Synthesis of pyrrole derivatives by palladium-catalyzed cyclization of γ,δ-unsaturated ketone o-pentafluorobenzoyloximes
Tsutsui, Hironori,Kitamura, Mitsuru,Narasaka, Koichi
, p. 1451 - 1460 (2007/10/03)
Various pyrrole derivatives are synthesized from γ,δ-unsaturated ketone O-pentafluorobenzoyloximes by treatment with catalytic amounts of Pd(PPh3)4 and triethylamine via alkylideneaminopalladium(II) intermediates generated by oxidative addition of the oximes to the Pd(0) complex.
Synthesis of pyrrole derivatives by the heck-type cyclization of γ,δ-unsaturated ketone O-pentafluorobenzoyloximes
Tsutsui, Hironori,Narasaka, Koichi
, p. 45 - 46 (2007/10/03)
Substituted pyrroles are synthesized from γδ-unsaturated ketone O-pentafluorobenzoyloximes by the intramolecular Heck-type amination of the olefinic moiety catalyzed by Pd(PPh3)4.