22057-80-3Relevant articles and documents
The Concept of Photozymes: Short Peptides with Photoredox Catalytic Activity for Nucleophilic Additions to α-Phenyl Styrenes
Sack, Daniel,Wagenknecht, Hans-Achim
, p. 6400 - 6407 (2021/11/18)
Conventional photoredox catalytic additions of alcohols to olefins require additives, like thiophenol, to promote back electron transfer. The concept of “photozymes” assumes that forward and backward electron transfer steps in a photoredox catalytic cycle
Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
Lei, Chuanhu,Yip, Yong Jie,Zhou, Jianrong Steve
supporting information, p. 6086 - 6089 (2017/05/08)
Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.
Microwave-assisted, Pd(0)-catalyzed cross-coupling of diazirines with aryl halides
Zhao, Xia,Wu, Guojiao,Yan, Chong,Lu, Kui,Li, Hui,Zhang, Yan,Wang, Jianbo
supporting information; experimental part, p. 5580 - 5583 (2011/02/23)
Pd(0)-catalyzed cross-coupling reactions of diazirines with aryl halides under microwave heating conditions afford a series of substituted olefins. A reaction mechanism involving the migratory insertion of the Pd carbene intermediate is proposed.