220573-01-3

Basic information

• Product Name: [(1R,4S,4aR,5R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl]-carbamic acid benzyl ester
• Synonyms: [(1R,4S,4aR,5R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl]-carbamic acid benzyl ester
• CAS NO: 220573-01-3
• Molecular Weight: 427.659
• Mol File: 220573-01-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1R,4S,4aR,5R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl]-carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(1R,4S,4aR,5R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl]-carbamic acid benzyl ester(220573-01-3)
• EPA Substance Registry System: [(1R,4S,4aR,5R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yl]-carbamic acid benzyl ester(220573-01-3)

Safety Data

• Hazardous Substances Data: 220573-01-3(Hazardous Substances Data)

Upstream product

• 220572-99-6 (1R,4S,4aR,5S,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-ol 
• 171824-23-0 (-)-(1S,4R,4aS,5R,8aR)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8a-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one 
• 501-53-1 benzyl chloroformate 
• 220573-00-2 ((1S,4R,4aS,5R,8R,8aR)-8-Azido-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yloxy)-tert-butyl-dimethyl-silane 

Downstream Products

• 220573-04-6 [(1R,6R)-6-(Benzyl-benzyloxycarbonyl-amino)-cyclohex-2-enyl]-acetic acid methyl ester 
• 220573-03-5 Benzyl-((1R,4R)-4-hydroxy-cyclohex-2-enyl)-carbamic acid benzyl ester 
• 220573-05-7 (3aR,7aR)-1-Benzyl-1,3,3a,6,7,7a-hexahydro-indol-2-one 
• 220573-02-4 [(1R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyl]-carbamic acid benzyl ester 

Relevant articles and documents

An enantio- and diastereoselective synthesis of (-)-isoretronecanol and (+)-trachelanthamidine from a meso precursor

Two diastereomeric pyrrolizidine alkaloids, (-)-isoretronecanol and (+)- trachelanthamidine, have been synthesized in an enantio- and diastereoselective manner starting from a meso precursor via a catalytic asymmetrization.